TiO2 and ZrO2 inB2O3 - MgO -SiO2 crystallizationprocess , relationresultForlha.sample1 ,b~mple2 ,c.sample3 Wang Minquan,l Ti4 and zT4+that Chun ,small radius ,charge high ,powerful ,easy polarization around the oxygen ions in order to establish the shield ,thereby promoting phase .
Phase is the crystallization of the school to provide the driving force ,phase generated interface for nucleation of the crystal phase and provide a favorable nucleation bit ,make as nucleating agent composition enriched in two phases ,phase ,and then by it from the liquid phase to phase ,and crystal pulling out of l .
Nucleating agent to promote crystallization effect depending on the cation size and charge ,ugg italia (http://www.uggsaldi.net),high intensity of small cationic ,than the low field intensity cation more carefully to be orderly holding column oxygen ions surrounded so small cations are more prone to ordered crystal structure transition of L T field strength (I2=8.
7 )than Z + ( 2=63 ll ,so TiO2 reduces the crystallization activation energy than ZrO2 significantly .Structure to join TiO2 tongue the spectrum ( Figure 5) appeared on the 490cm ~,533cm ~,930cmI1and 12~5cmIlbelong to B205 characteristic vibrationl Bai .
At the same time appear in 540~590cmI1 BO3bending vibration,in 900 ,~950cm BO3 symmetric stretching ,1000 ~ 1260cm ina 1BOa of theasymmetric stretching Description of slag containing and BOa groupsmore, indicating which of the two groups in favor of 2M o.
B2Oa and 3O· cellar;precipitation of.XRD has also confirmed that the accession to the O2 sample No. 1isnot added to precipitate more 2Mgo· ;B203 and aMgO·B2O3 (Figure 4 )Journal of materials research Volume 12 2E ,( o ) Fig 4 the sampleat 750 ℃ isothermalannealing 1H,nike air max 2012 (http://www.nike-airmax.it/uomo-nike-air-max-nike-air-max-2012-c-6_57.html),in 8501C 30-~i-two heat treatment xRD harmonic Fig.
4XRDpatternsofsamplesannealedat75O ℃ forlhandheatedat850 ℃for30mi Ⅱexport/ cm . Fig 5 infrared spectrum of sampleF.5IRspectr~ofsamples1 (a ) and3 (b ) conclusion TiO2 and Zr0 asprismatic agents after joining ,promote phase separation ,reduces the crystallization activation energy, facilitates table boron component with 2M0· ;B2o3 and 31%~O-B2O3 exhalation,are effective nucleation Jing .
Join PA 2can change thestructure of molten slag ,produce more in favor of 2Mg0· ;B2Os and M0· ;BzO5 andBOs groups B203 precipitation .In reference P.x.ZbanK ,z.T.Sul ,MetallMaWrTr~m1.
B26 (2),345(1995)JY.Hsu .R.F.Speyer ,JAmCe~eauSoc.72 (12),ropa Abercrombie (http://www.abercrombiemexico.net),2334(19~9)w.zdanjw ,J.Am.Ceram.Soc ( the 5_6) 163(19Ys) G.Pdge , (3).133 (I~ ) M.Cwinberg ,JAmuCeram.Soc.74 (
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Ray ,w.H.I-luang ,D.E.Day ,J.Am.c ,m.Soc. ( 1) 60(w.A.Jonhson ,1991)nF.M .Trans.Amer.Imst.Min.Enm135416 (1939)M.Avrmi ,J.Phys.Chem.l2 ),1103(1939);8(2),2l2(194O) ;9(2), (1941)N.P.BansBI ,J.
Therma2.Ana1.29 (1).1I~ ( 1984)Wang Minquan .Case Zhi toughness .Cheng Feng . Silicon dare salt transport report ,2(4),l d ( 1983)Li Mu Jiaqia . Silicon salt Sinica, 6(4),2(19)F.W.
McMBm~ Wang Renggan sou crystal La glass China Building Industry Press .1983 )P.103 ;p16 Peng Wen WTO ,Liu Gaokui. Mine shaft rainbow spectrum ring set ( Beijing Science Press .
1982 )P-179 Tochigisouth such as the chief editor . Inorganic non overlapping metal well past l try Hao Fang ( Wu to put on ,Wu to Industrial University Press, 199O) P273 ,uca= §
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